原著論文

  1. Sequential C–F Bond Transformation of the Difluoromethylene Unit in Perfluoroalkyl Groups: A Combination of Fine-Tuned Phenothiazine Photoredox Catalyst and Lewis Acid. Sugihara, N.; *Nishimoto, Y.; Osakada, Y.; Fujitsuka, M.; Abe, M.; *Yasuda, M. Angew. Chem. Int. Ed. 2024, e202401117. DOI: 10.1002/anie.202401117.
  2. Photocatalytic Aldehyde C–H Bond Phosphonioethylation with Vinylphosphonium Bromide. Mori, H.; Yoshida, M.; *Sawamura, M.; *Masuda, Y. Asian J. Org. Chem., 2024, 13, e202300532. DOI: 10.1002/ajoc.202300532.
  3. Product Selectivity Control under Acidic and Basic Conditions on Oxidative Transformation of 1,3-Dicarbonyls Using Sodium Hypochlorite Pentahydrate. *Kirihara, S.; Sakamoto, Y.; Tanaka, T.; Kawaia, T.; Okada, T.; Kimura, Y.; *Takizawa, S. Synthesis 2024, in press. DOI: 10.1055/a-2260-0282.
  4. Photocatalyzed C–F Bond Heteroarylation of Trifluoromethyl­arenes with Heteroarenes: Two Roles of Bu3SnI as Fluoride Ion Scavenger and Activator for Photocatalyst. Sugihara, N.; Abe, M.; *Nishimoto, Y.; *Yasuda, M. Synthesis 2024, in press. DOI: 10.1055/a-2235-1380.
  5. N-2,6-Di(isopropyl)phenyl-2-azaphenalenyl Radical Cations. Inoue, T.; Matsuura, Y.; Horii, K.; *Konishi, A.; Nishida, J. *Yasuda, M.; Kawase, T. Chem. Commun. 2024, 60, 1735-1738. DOI: 10.1039/d3cc05968e.
  6. γ‑Butyrolactone Synthesis from Allylic Alcohols Using the CO2 Radical Anion. Mangaonkar, S. R.; Hayashi, H.; Kanna, W.; Debbarma, S.; Harabuchi, Y.; *Maeda, S.; *Mita, T.
    Precis. Chem. 2024, 2, asap. DOI: 10.1021/prechem.3c00117.
  7. Continuous-Flow Enantioselective Hydrogenative Enyne Cyclization with Chiral Heterogeneous Rh Catalysts. Saito, Y.; Sato, Y.; *Kobayashi, S. ACS Catal. 2024, 2024, 14, 2202–2206. DOI: 10.1021/acscatal.3c05868.
  8. Strategic use of crude H2 for the catalytic reduction of carbonyl compounds. Sakuraba, M.; Ogoshi, S.; *Hoshimoto, Y. Tetrahedron Chem 2024, 9, 100059. DOI: 10.1016/j.tchem.2023.100059.
  9. Light-induced autoxidation of aldehydes to peracids and carboxylic acids. Salem, M. S. H.; Dubois, C.; Takamura, Y.; Kitajima, A.; Kawai, T.; *Takizawa, S.; *Kirihara, M. Green Chem. 2024, 26, 375-383. DOI: 10.1039/d3gc02951d.
  10. Continuous-Flow Enantioselective Hydroacylations under Heterogeneous Chiral Rhodium Catalysts. Saito, Y.; *Kobayashi, S. Angew. Chem. Int. Ed. 2024, 63, e202313778. DOI:　10.1002/anie.202313778.
  11. Synthesis and Characterization of Hexafluorocyclopentane-Bridged Bisbutatrienes as Models for Longer Cumulenes: Various Transformations for the Constructions of π-Conjugated Frameworks. *Konishi, A.; Imai, S.; Satake, S.; Chiba, K.; *Yasuda, M. Chem. Eur. J. 2023, 29, e202301255. DOI: 10.1002/chem.202301255.
  12. Synthesis and Characterization of Dibenzothieno[a,f]pentalenes Enabling Large Antiaromaticity and Moderate Open-Shell Character through a Small Energy Barrier for Bond-Shift Valence Tautomerization. Mizuno, Y.; Nogata, A.; Suzuki M.; Nakayama, K.; Hisaki, I.; *Kishi, R.; *Konishi, A.; *Yasuda, M. J. Am. Chem. Soc. 2023, 145, 20595-20609. DOI: 10.1021/jacs.3c07356.
  13. Total Synthesis of Taxol Enabled by Intermolecular Radical Coupling and Pd-Catalyzed Cyclization. Watanabe, T.; Oga, K.; Matoba, H.; Nagatomo, M.; *Inoue, M. J. Am. Chem. Soc. 2023, 145, 25894–25902. DOI: 10.1021/jacs.3c10658.
  14. Continuous-Flow Enantioselective Hydroacylations under Heterogeneous Chiral Rhodium Catalysts. Saito, Y.; *Kobayashi, S. Angew. Chem. Int. Ed. 2023, e202313778. DOI: 10.1002/anie.202313778.
  15. Light-induced autoxidation of aldehydes to peracids and carboxylic acids. Salem, M. S. H.; Dubois, C.; Takamura, Y.; Kitajima, A.; Kawai, T.; *Takizawa, S.; *Kirihara, M. Green Chem. 2024, 26, 375-383. DOI: 10.1039/D3GC02951D.
  16. Data-driven Electrochemical One-pot Synthesis of Double Hetero[7]dehydrohelicene. Salem, M. S. H.; Sharma, R.; Khalid, Md. I.; Sasi, M.; Amasaki, R.; Imai, Y.; Arisawa, M.; *Takizawa, S. Electrochemistry 2023, 91, 112015. DOI: 10.5796/electrochemistry.23-67092.
  17. N-Borane-Substituted Cyclic Phosphine Imides (BCPIs). Nagai, S.; Hinogami, T.; *Ogoshi, S.; *Hoshimoto, Y. Bull. Chem. Soc. Jpn. 2023, 96, 1346-1353. DOI: 10.1246/bcsj.20230228.
  18. Remote Back Strain: A Strategy for Modulating the Reactivity of Triarylboranes. Sakuraba, M.; Morishita, T.; Hashimoto, T.; *Ogoshi, S.;  *Hoshimoto, Y. Synlett 2023, 34, 2187-2192. DOI: 10.1055/a-2110-5359.
  19. Reversible Modulation of the Electronic and Spatial Environment around Ni(0) Centers Bearing Multifunctional Carbene Ligands with Triarylalumin. Yamauchi, Y.; Mondori, Y.; *Uetake, Y.; Takeichi,Y.; Kawakita, T.; Sakurai, H.; *Ogoshi, S.; *Hoshimoto, Y. J. Am. Chem. Soc. 2023, 145, 16938-16947. DOI: 10.1021/jacs.3c06267.
  20. Reversible Boron-insertion into Aromatic C–C Bonds. Kuroki, K.; Ito, T.; *Takaya, J. Angew. Chem. Int. Ed. 2023, 62, e202312980. DOI: 10.1002/anie.202312980.
  21. Origin of Reactivity Difference between Phosphines and Phosphinites in Ru-Catalyzed Phosphorus-Directed Sp 2 C–H Borylation: Mechanistic Study and Improvement of Reaction Conditions. Homma, Y.; Fukuda, K.; Ueno, R.; Iwasawa, N.; *Takaya, J. Bull. Chem. Soc. Jpn. 2023, 96, 842–848. DOI: 10.1246/bcsj.20230111.
  22. Axially Chiral Borinic Acid Catalysts: Design, Synthesis, and Application in Alkylative Desymmetrization of 1,2-Diols. Chikashige, Y.; Takehara, T.; Matsuzaki, T.; Suzuki, T.; Murai, K.; *Arisawa, M.; *Sako, M. J. Org. Chem. 2023, 88, 14178-14183 DOI: 10.1021/acs.joc.3c01143.
  23. Photocatalytic 1,2-Phosphorus-Migrative [3+2] Cycloaddition of Tri(t-butyl)phosphine with Terminal Alkynes. *Masuda, Y.; Ikeshita, D.; Higashida, K.; Yoshida, M.; Ishida, N.; Murakami, M.; *Sawamura, M. J. Am. Chem. Soc. 2023, 145, 19060–19066. DOI: 10.1021/jacs.3c06760.
  24. Sequence-selective Three-component Reactions of Alkyltrifluoroborates with α,β-Unsaturated Carbonyl Compounds and Vinylphosphonium Salts. Yoshida, M.; *Sawamura, M.; *Masuda, Y. Org. Chem. Front. 2023, 10, 3654-3661. DOI: 10.1039/D3QO00631J.
  25. Chemoselectivity Change in Catalytic Hydrogenolysis enabling Urea-reduction to Formamide/Amine over More Reactive Carbonyl Compounds. *Iwasaki, T.; Tsuge, K.; Naito, N.; *Nozaki, K. Nat. Commun. 2023, 14, 3279. DOI: 10.1038/s41467-023-38997-2.
  26. Palladium-catalyzed copolymerization of ethylene or propylene with norbornene carboxylic acids and their esters. Tsuge, K.; Lau, K.; Hirooka, Y.; Iwasaki, T.; Yokomizo, K.; *Nozaki, K. Polymer 2023, 281, 126116. DOI: 10.1016/j.polymer.2023.126116.
  27. Continuous-flow Reductive N-Methylation with Highly Active Heterogeneous Pd Catalysts and Sequential-flow Synthesis of N-Monomethyl Amines. Saito, Y.; Senzaki, T.; Nishizawa, K.; *Kobayashi S. Green Chem. 2023, 25, 7524-7528. DOI: 10.1039/D3GC01472J.
  28. Computational Mechanistic Study on Intramolecular Triple Cyclization of 1-Biphenylethynyl-2-phenylethynylbenzenes Giving Spiro Fluorene-Phenylenevinylenes by Dual Catalysis *Nagashima, Y.; Ouchi, S.; Inoue, T.; *Tanaka, K. Bull. Chem. Soc. Jpn. 2023, 96, 717–723. DOI: 10.1246/bcsj.20230105.
  29. Catalytic stereoselective synthesis of doubly, triply and quadruply twisted aromatic belts. Nogami, J.; *Hashizume, D.; Nagashima, Y.; Miyamoto, K.; Uchiyama, M.; *Tanaka, K. Nat. Synth. 2023, 2, 888–897. DOI: 10.1038/s44160-023-00318-2.
  30. Antifouling Brominated Diterpenoids from Japanese Marine Red Alga Laurencia venusta Yamada Fukada, R.; *Yamagishi, Y.; Nagasaka, M.; Osada, D.; Nimura, K.; Oshima, I.; Tsujimoto, K.; Kirihara, M.; Takizawa,　S.; Kikuchi, N.; Ishii, T.; *Kamada, T. Chem. Biodiversity 2023, 20, e202300888. DOI: 10.1002/cbdv.202300888.
  31. Light-controlled pKa Value of Chiral Brønsted Acid Catalysts in Enantioselective Aza-Friedel–Crafts Reaction Krishnan, C. G.; Kondo, M.; Yasuda, Y.; Fan, D.; Nakamura, K.; Wakabayashi, Y.; Sasai, H.; *Takizawa, S. Chem. Commun. 2023, 59, 9956. DOI: 10.1039/D3CC02719H.
  32. Bayesian Optimization-Assisted Screening to Identify Improved Reaction Conditions for Spiro-Dithiolane Synthesis Kondo, M.; Wathsala, H. D. P.; Ishikawa, K.; Daisuke Yamashita, D.; Miyazaki, T.; Ohno, Y.; Sasai, H.; Washio, T.; *Takizawa, S. Molecules 2023, 28, 5180. DOI: 10.3390/molecules28135180.
  33. Directed Metalation of 1-Cuneanecarboxamide: Simple Route to 1,2-Disubstituted Cuneanes. Takebe, H.; *Matsubara, S. Chem. Lett. 2023, 52, 358–360. DOI: 10.1246/cl.230101.
  34. Machine Learning that Proposes Reaction Conditions and Yields for Wittig-type Methylenation of Aldehydes with Bis(iodozincio)methane in a Flow-microreactor. Maruoka, T.; Yada, A.; Satp, K.; *Matsubara, S. Chem. Lett. 2023, 52, 397–399. DOI: 10.1246/cl.230133.
  35. Visible-Light-Induced Aminochlorination of Alkenes. Mejri, E.; Higashida, K.; Kondo, Y.; Nawachi, A.; Morimoto, H.; Ohshima, T.; *Sawamura, M.; *Shimizu, Y. Org. Lett. 2023, 25,  4581–4585. DOI: 10.1021/acs.orglett.3c01645.
  36. Revisiting the Electrochemical Carboxylation of Naphthalene with CO2: Selective Monocarboxylation of 2-Substituted Naphthalenes. Rawat, V. K.; Hayashi, H.; Katsuyama, H.; Mangaonkar, S. R.; *Mita, T. Org. Lett. 2023, 25, 4231–4235. DOI: 10.1021/acs.orglett.3c01033.
  37. Heteroannulation of Bicyclobutane Derivatives via Au-catalyzed Hydration to Enol Ethers and Intramolecular Cyclization Giving Spirocyclobutanes. Takatsuki, M.; Aoyama, H.; Murai, K.; *Arisawa, M.; *Sako, M. Chem. Commun. 2023, 59, 7467-7470. DOI: 10.1039/D3CC01955A.
  38. Synthesis of Bicyclo[1.1.1]pentane (BCP)-Based Straight-Shaped Diphosphine Ligands. Takano, H.; Katsuyama, H.; Hayashi, H.; Harukawa, M.; Tsurui, M.; Shoji, S.; Hasegawa, Y.; Maeda, S.; *Mita, T. Angew. Chem., Int. Ed. 2023, 62, e202303435. DOI: 10.1002/anie.202303435.
  39. Electrochemical Synthesis of Sultone Derivatives via Dehydrogenative C-O Bond Formation. *Mitsudo, K.; Okumura, Y.; Yohena, K.; Kurimoto, Y.; Sato, E.; *Suga, S. Org. Lett. 2023, 25, 3476–3481. DOI: 10.1021/acs.orglett.3c01062.
  40. Electrochemical Cross-Coupling Reactions between Arylboronic Esters and Aryllithiums Using NaBr as a Halogen Mediator. *Mitsudo, K.; Shigemori, K.; Shibata, T.; Mandai, H.; Sato, E.; *Suga, S. Synthesis 2023, 55, 2999-3004. DOI: 10.1055/a-2034-9821.
  41. Electrochemical Carbon-Ferrier Rearrangement Using a Microflow Reactor and Machine Learning-Assisted Exploration of Suitable Conditions. *Sato, E.; Tachiwaki, G.; Fujii, M.; Mitsudo, K.; Washio, T.; Takizawa, S.; *Suga, S. Org. Process Res. Dev. 2023, ASAP. DOI: 10.1021/acs.oprd.2c00267.
  42. Protocol for efficient dearomatization of N-heteroaromatics with halogen(I) complex catalyst. Oishi, S.; Fujinami, T.; Masui, Y.; Suzuki, T.; Kato, M.; Ohtsuka, N.; * Momiyama, N. STAR Protocols 2023, 4, 102140. DOI: 10.1016/j.xpro.2023.102140.
  43. Merging the Norrish Type I Reaction and Transition Metal Catalysis: Photo- and Rh-Promoted Borylation of C–C σ-Bonds of Aryl Ketones, Fujimaki, Y.; Iwasawa, N.; *Takaya, J. Chem. Sci. 2023, 14, 1960–1965. DOI: 10.1039/d2sc06801j.
  44. Chiral Auxiliary-Directed Site-Selective Deprotonation of the Cubane Skeleton, Takebe, H.; Yoshino, N.; Shimada, Y.; Williams, C.; *Matsubara, S. Org. Lett. 2023, 25, 27-30. DOI: 10.1021/acs.orglett.2c03659.
  45. Chromium-Catalyzed syn-Selective Ring-Opening Aryl-/Alkylation of 7-Oxabenzonorbornadiene Derivatives with Grignard Reagents. Nishi, K.; *Tsurugi, H.; *Mashima, K. ACS Catal, 2023, 13, 3093-3100. DOI: 10.1021/acscatal.2c05029.
  46. Chromium-catalyzed olefination of arylaldehydes with haloforms assisted by 2,3,5,6-tetramethyl-N,N’-bis(trimethylsilyl)-1,4-dihydropyrazine. Nishi, K.; *Tsurugi, H.; *Mashima, K. Chem. Commun. 2023, 59, 908-911. DOI: 10.1039/D2CC06104J.
  47. Isolation and structure determination of allopteridic acids A-C and allokutzmicin from an unexplored actinomycete of the genus Allokutzneria. Liu, C.; Zhang, Z.; Fukaya, K.; Oku, N.; Harunari, E.; Urabe, D.; *Igarashi, Y. J. Antibiot. 2023, 76, 305-315. DOI: 10.1038/s41429-023-00611-4.
  48. Species-specific secondary metabolism by actinomycetes of the genus Phytohabitans and discovery of new pyranonaphthoquinones and isatin derivatives. Triningsih, D. W.; Harunari, E.; Fukaya, K.; Oku, N.; Urabe, D.; *Igarashi, Y. J. Antibiot. 2023, 76, 249-259. DOI: 10.1038/s41429-023-00605-2.
  49. Oxidation and Reduction Pathways in the Knowles Hydroamination via a Photoredox-Catalyzed Radical Reaction. *Harabuchi, Y.; Hayashi, H.; Takano, H.; Mita, T.; *Maeda, S. Angew. Chem., Int. Ed. 2023, 62, e202211936. DOI: 10.1002/anie.202211936.
  50. Synthesis of polysubstituted enamides by hydrogen atom transfer alkene isomerization using dual cobalt/photoredox catalysis. Seino, Y.; Yamaguchi, Y.; Suzuki, A.; Yamashita, M.; Kamei, Y.; Kamiyama, F.; Yoshino, T.; *Kojima, M.; *Matsunaga, S. Chem. Eur. J. 2023, 29, e202300804. DOI: 10.1002/chem.202300804.
  51. Formation of isolable dearomatized [4 + 2] cycloadducts from benzenes, naphthalenes, and N-heterocycles using 1,2-dihydro-1,2,4,5-tetrazine-3,6-diones as arenophiles under visible light irradiation. Ikeda, K.; Kojima, R.; Kawai, K.; Murakami, T.; Kikuchi, T.; Kojima, M.; *Yoshino, T.; *Matsunaga, S. J. Am. Chem. Soc. 2023, 145, 9326-9333. DOI: 10.1021/jacs.3c02556.
  52. An electron-deficient CpE iridium(III) catalyst: Synthesis, characterization, and application to ether-directed C–H amidation. Tomita, E.; Kojima, M.; Nagashima, Y.; Tanaka, K.; Sugiyama, H.; Segawa, Y.; Furukawa, A.; Maenaka, K.; Maeda, S.; *Yoshino, T.; *Matsunaga, S. Angew. Chem. Int. Ed. 2023, 62, e202301259. DOI: 10.1002/anie.202301259.
  53. Iron/photosensitizer-catalyzed directed C–H activation triggered by the formation of an iron metallacycle. Kato, Y.; Yoshino, T.; *Matsunaga, S. ACS Catal. 2023, 13, 4552–4559. DOI: 10.1021/acscatal.3c00381.
  54. Noble-metal-free C–H allylation of tetrahydroisoquinolines using a cobalt-organophotoredox dual catalyst system. Sato, S.; Sasaki, W.; Sekino, T.; Yoshino, T.; *Kojima, M.; *Matsunaga, S. Chem. Pharm. Bull. 2023, 71, 79–82. DOI: 10.1248/cpb.c22-00520.
  55. Photocatalytic deuterium atom transfer deuteration of electron-deficient alkenes with high functional group tolerance. Suzuki, A.; Kamei, Y.; Yamashita, M.; Seino, Y.; Yamaguchi, Y.; Yoshino, T.; *Kojima, M.; *Matsunaga, S. Angew. Chem. Int. Ed. 2023, 62, e202214433. DOI: 10.1002/anie.202214433.
  56. 4-Chloro-2-azaadamantane N-Oxyl (4-Cl-AZADO): A Readily Preparable Organocatalyst for NOx Co-catalyzed Aerobic Alcohol Oxidation. Nagasawa, S.; Sasano, Y.; *Iwabuchi, Y. Asian J. Org. Chem. 2023, 12, e202300031. DOI: 10.1002/ajoc.202300031.
  57. Identification of the Optimal Framework for Nitroxyl Radical/Hydroxylamine in Copper-Cocatalyzed Aerobic Alcohol Oxidation. Toda, M.; Sasano, Y.; Takahashi, M.; Fujiki, S.; Kasabata, K.; Ono, T.; Sato, K.; Kashiwagi, Y.; *Iwabuchi, Y. J. Org. Chem. 2023, 88, 1434–1444. DOI: 10.1021/acs.joc.2c02327.
  58. Electrochemical reactions of highly active nitroxyl radicals with thiol compounds. Kumano, M.; Sugiyama, K.; Sato, F.; Komatsu, S.; Watanabe, K.; Ono, T.; Yoshida, K.; Sasano, Y.; Iwabuchi, Y.; Fujimura, T.; *Kashiwagi, Y.; *Sato, K. Anal. Sci. 2023, 39, 369–374. DOI: 10.1007/s44211-022-00246-9.
  59. Amine-catalyzed Synthesis of Fluorine-containing Polymers through Halogen Bonding. Kanbara, T.; Arase, M.; Tanaka, M.; Yamaguchi, A.; Tagami, K,;*Yajima, T. Chem Asian J. 2023, e202300035. DOI: 10.1002/asia.202300035.
  60. Syntheses and Redox Properties of Carboxylate-ligated Hexanuclear Ce(IV) Clusters and Their Photo-induced Homolysis of the Ce(IV)-ligand Covalent Bond. Kawakami, T.; Tamaki, S.; Shirase, S.; *Tsurugi, H.; *Mashima, K. Inorg. Chem. 2022, 61, 20461-20471. DOI: 10.1021/acs.inorgchem.2c03163.
  61. Pyrazine Alkylation with Aldehydes and Haloalkanes Using N,N‘-Bis(trimethylsilyl)-1,4-dihydropyrazine Derivatives. *Tsurugi, H.; Matsuno, M.; Kawakami, T.; *Mashima, K. Eur. J. Org. Chem. 2022, e202200862. DOI: 10.1002/ejoc.202200862.
  62. Metal-free visible-light-induced hydroxyperfluoroalkylation of conjugated olefins using enamine catalyst. Tagami, K,; Ofuji, Y.; Kanbara, T.; *Yajima, T. RSC Adv. 2022, 12, 32790–32795. DOI: 10.1039/D2RA06679C.
  63. Eosin Y catalyzed Visible-Light-Induced Hydroperfluoroalkylation of Electron-Deficient Alkenes; Shigenaga, S.; Shibata, H.; Tagami, K.; Kanbara, T.; *Yajima, T. J. Org. Chem. 2022, 87, 14923–14929. DOI: 10.1021/acs.joc.2c01827.
  64. Direct α-Trifluoromethylthiolation of Carboxylic Acids Enabled by Boron Catalysis. Sun, K.; *Huang, C.-H. D.; Sawamura, M.;*Shimizu, Y. Synlett 2023, xx, xxxx–xxxx. DOI: 10.1055/a-2071-4465.
  65. Total Synthesis of (+)-Shearilicine. Kim, D. E.; Zhu, Y.; Harada, S.; Aguilar, I.; Cuomo, A. E.; Wang, M.; *Newhouse, T. R. J. Am. Chem. Soc. 2023, 145, 4394–4399. DOI: 10.1021/jacs.2c13584.
  66. Tris(pentafluorophenyl)borane-Catalyzed Stereospecific Bromocyanation of Styrene Derivatives with Cyanogen Bromide. *Kiyokawa, K.; Noguchi, I.; Nagata T.; *Minakata, S. Org. Lett. 2023, 25, 2537–2542. DOI: 10.1021/acs.orglett.3c00727.
  67. Stereospecific Oxycyanation of Alkenes with Sulfonyl Cyanide. *Kiyokawa, K.; Ishizuka, M.; *Minakata, S. Angew. Chem. Int. Ed. 2023, 62, e202218743. DOI: 10.1002/anie.202218743.
  68. α-Amination of Carbonyl Compounds by Using Hypervalent Iodine-Based Aminating Reagents Containing a Transferable (Diarylmethylene)‍amino Group. Okumatsu, D.; Kawanaka, K.; Kainuma, S.; *Kiyokawa, K.; *Minakata, S. Chem. Eur. J. 2023, 29, e202203722. DOI: 10.1002/chem.202203722.
  69. Design, synthesis, and visible-light-induced non-radical reactions of dual-functional Rh catalysts. Ouchi, S.; Inoue, T.; Nogami, J.; *Nagashima, Y.; *Tanaka, K. Nat. Synth. 2023, 2,  535–547. DOI: 10.1038/s44160-023-00268-9.
  70. Rhodium-Catalyzed Chemo-, Regio-, Diastereo-, and Enantioselective Intermolecular [2+2+2] Cycloaddition of Three Unsymmetric 2π Components. Shimotsukue, R.; Fujii, K.; Sato, Y.; Nagashima, Y.; *Tanaka, K. Angew. Chem. Int. Ed. 2023, 62, e202301346. DOI: 10.1002/anie.202301346.
  71. Dearomative triple elementalization of quinolines driven by visible light. Ishigaki, S.; *Nagashima, Y.; Yukimori, D.; Tanaka, J.; Matsumoto, T.; Miyamoto, K.; *Uchiyama, M.; *Tanaka, K. Nat. Commun. 2023, 14, 652. DOI: 10.1038/s41467-023-36161-4.
  72. Room Temperature Fluoranthene Synthesis through Cationic Rh(I)/H8-BINAP-Catalyzed [2 + 2 + 2] Cycloaddition: Unexpected Acceleration due to Noncovalent Interactions. Abe, R.; *Nagashima, Y.; Tanaka, J.; *Tanaka, K. ACS Catal. 2023, 13, 1604–1613. DOI: 10.1021/acscatal.2c05683.
  73. Less Is More: N(BOH)2 Configuration Exhibits Higher Reactivity than the B3NO2 Heterocycle in Catalytic Dehydrative Amide Formation. Opie, C. R.; *Noda, H.; Shibasaki, M.; *Kumagai, N. Org. Lett. 2023, 25, 694–697. DOI: 10.1021/acs.orglett.2c04382.
  74. Asymmetric Syn-Selective Vinylogous Addition of Butenolides to Chromones via Al-Li-BINOL Catalysis. Samanta, S.; Cui, J.; Noda, H.; *Watanabe, T.; *Shibasaki, M. J. Org. Chem. 2023, 88, 1177–1184. DOI: 10.1021/acs.joc.2c02731.
  75. One-Electron Injection-triggered Radical Reaction of Alkyl Benzoates Promoted by 1,4-Bis(diphenylamino)benzene Photocatalysis. T. Koike,* R. Okumura, T. Kato, M. Abe, M. Akita. ChemCatChem 2023, 15, e202201311. DOI: 10.1002/cctc.202201311.
  76. Organocatalytic Direct Enantioselective Hydrophosphonylation of N-Unsubstituted Ketimines for the Synthesis of α-Aminophosphonates. Yamada, K.; Kondo, Y.; Kitamura, A.; Kadota, T.; *Morimoto, H.; *Ohshima, T. ACS Catal. 2023, 13, 3158–3163. DOI: 10.1021/acscatal.2c05953.
  77. O- and N-Selective Electrophilic Activation of Allylic Alcohols and Amines in Pd-Catalyzed Direct Alkylation. Lin, L.; Kataoka, S.; Hirayama, K.; Shibuya, R.; Watanabe, K.; Morimoto, H.; *Ohshima, T. Chem. Pharm. Bull. 2023, 71, 101–106. DOI: 10.1248/cpb.c22-00745.
  78. Palladium(0)-Catalyzed Anti-Selective Addition-Cyclizations of Alkynyl Electrophiles. *Tsukamoto, H.; Ito, K.; Ueno, T.; Shiraishi, M.; Kondo, Y.; Doi, T. Chem. Eur. J. 2023, 29, e202203068. DOI: 10.1002/chem.202203068.
  79. Photoredox/HAT-Catalyzed Dearomative Nucleophilic Addition of the CO2 Radical Anion to (Hetero)Aromatics. Mangaonkar, S. R.; Hayashi, H.; Takano, H.; Kanna, W.; Maeda, S.; *Mita, T. ACS Catal. 2023, 13, 2482-2488. DOI: 10.1021/acscatal.2c06192.
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